Sodium benzoate
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Sodium benzoate

Preservatives
532-32-1
E211
C₆H₅COONa
$1.40 ~ $2.10
Food
Free sample from 100g(NF)
One unit of:25kg/bag
25kg/bag
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Product Info

What is Sodium benzoate?

Sodium benzoate is a widely used food preservative that inhibits the growth of mold, yeast, and bacteria, primarily in acidic foods and beverages.

How is Sodium benzoate made?

Step No. Production Stage Key Action Control Point & Note
1 Raw Material Charging Liquid Toluene and a catalyst (e.g., cobalt salt) are precisely measured and fed into a high-pressure reactor. Control Point: Purity of Toluene must meet specifications. Accurate dosing of raw materials and catalyst is crucial for reaction efficiency.
2 Liquid-Phase Oxidation The Toluene is oxidized using purified compressed air at high temperature and pressure, converting it into crude Benzoic Acid. Control Point: Strict control of temperature (150-250°C) and pressure (5-15 atm) is critical for yield and safety. This is the core chemical conversion step.
3 Benzoic Acid Purification Crude Benzoic Acid is purified, typically via vacuum distillation, to remove unreacted Toluene, by-products, and catalyst residues. Control Point: The purity of the intermediate Benzoic Acid must be high to ensure the final product meets food-grade standards.
4 Neutralization The purified Benzoic Acid is dissolved in water and neutralized with a high-purity sodium source, like Sodium Hydroxide or Sodium Carbonate, to form a Sodium Benzoate solution. Control Point: The reaction pH must be carefully controlled to a neutral or slightly alkaline state (typically 7.5-8.5) to ensure complete conversion.
5 Decolorization & Filtration The Sodium Benzoate solution is treated with activated carbon to remove color impurities and then passed through fine filters. Control Point: The goal is a perfectly clear, colorless solution. The filtration step must remove all suspended particles, including the activated carbon.
6 Drying The purified solution is dried to remove water, yielding a solid product. Spray drying is a common method for producing a fine powder. Control Point: The final moisture content must be below the specified limit (e.g., <1.5%). Drying temperature is controlled to prevent product degradation.
7 Sizing (Sieving/Milling) The dried Sodium Benzoate is sieved to achieve the desired particle size (e.g., powder or granular). Milling may be used if necessary. Control Point: Particle size distribution is checked against product specifications. Metal detection is often performed at this stage.
8 Final Quality Control & Packaging The final product is tested for assay, purity, heavy metals, and other food-grade parameters. It is then packaged into sealed, labeled, food-safe containers. Control Point: Product must comply with all FCC (Food Chemicals Codex) or E211 specifications. The packaging area must be clean to prevent contamination.

Technical Specifications

CAS Number 532-32-1
Chemical Formula C₆H₅COONa
Solubility soluble in water (≈62 g/100 mL at 0–30 °C)
Storage Conditions cool, dark place
Shelf Life 24 Months

Applications & Usage

Common Applications:

food
beverages
pharmaceuticals
cosmetics
fireworks

Mechanism of action:

Parameter Sodium benzoate
Functional Category Antimicrobial Agent; Preservative
Key Ingredients Sodium Benzoate (E211)
Mechanism of Action In acidic conditions (pH < 4.5), sodium benzoate converts to its active, undissociated form, benzoic acid. This lipophilic molecule penetrates the microbial cell membrane. Inside the higher-pH cytoplasm, it dissociates, releasing protons that acidify the cell's interior. This intracellular pH drop inhibits key metabolic enzymes (e.g., phosphofructokinase), disrupting glycolysis and energy production, ultimately leading to microbial stasis or death.
Application Effect in Product Inhibits the growth of yeasts, molds, and some bacteria in acidic food and beverage systems. Extends shelf life and maintains product quality by preventing spoilage, off-flavors, and unwanted fermentation. Most effective in products like carbonated drinks, fruit juices, jams, jellies, and salad dressings.


Comparison:

Product Name Category/Type Key Features Strengths (vs peers) Weaknesses (vs peers) Best Use Cases Why Choose
Sodium benzoate Food Preservative (Antimicrobial) Salt of benzoic acid. Effective against yeast, mold, and some bacteria in acidic conditions. Highly cost-effective. Very stable and easy to dissolve. Extremely effective in high-acid products (pH below 4.5). Ineffective in neutral or alkaline products. Can impart a slight sharp taste. Can form benzene in the presence of ascorbic acid and UV light/heat. Carbonated soft drinks, fruit juices, salad dressings, pickles, jams, and condiments. For low-cost, effective preservation in highly acidic liquid or semi-solid foods.
Potassium sorbate Food Preservative (Antimicrobial) Salt of sorbic acid. Primarily inhibits the growth of mold and yeast. Effective over a wider pH range (up to 6.5) than benzoate. More neutral flavor profile. Less effective against bacteria. More expensive than sodium benzoate. Cheese, wine, yogurt, dried fruits, baked goods, jerky, and apple cider. For preserving less acidic products or when a neutral taste is critical.
Calcium propionate Food Preservative (Antimicrobial) Salt of propionic acid. Most effective against mold. Does not inhibit yeast, making it ideal for leavened baked goods. Very effective mold inhibitor. Narrow spectrum; not very effective against yeast or bacteria. Can sometimes add a slight cheesy flavor in high concentrations. Bread, tortillas, cakes, pastries, and other commercial baked goods. When the primary goal is to prevent mold in yeast-leavened products like bread.
Potassium benzoate Food Preservative (Antimicrobial) Potassium salt of benzoic acid. Functionally identical to sodium benzoate. Allows for "low sodium" or "sodium-free" product claims while providing the same preservation as sodium benzoate. More expensive than sodium benzoate. Shares the same pH limitations and potential for benzene formation. Low-sodium versions of acidic beverages, jams, sauces, and salad dressings. When the preservation properties of benzoate are required for a low-sodium product formulation.

Technical Documents

Available Documentation

spec sheet, COA available

Safety Data Sheet (SDS)

MSDS/SDS available

Certificate of Analysis (COA)

Quality assurance documentation

Technical Data Sheet

Detailed technical specifications